GS 537: Geochemistry and Geochemical Thermodynamics

Syllabus​

Chemical composition of the Earth and its constituent reservoirs; meteorite evidence; elementary statistics for geochemistry; major, minor and trace elements including rare earth elements; element partitioning between minerals and melts; oxide-element conversions; radioactivity and geochronology; chemical and isotopic fractionation; application of Rb-Sr and Sm-Nd isotope geochemistry to rock dating, petrogenesis, and crust-mantle evolution; mixing phenomena in elements and isotopes; related numericals.

Introduction to equilibrium thermodynamics; laws of thermodynamics; internal energy, heat capacity, enthalpy and entropy; Gibbs free energy and chemical potential; fugacity and activity; Raoult’s law and Henry’s law; ideal and non-ideal solutions; equilibrium constant; principles of geothermobarometry; aqueous solutions and solubility equilibria; activities of ionic species; construction of Eh-pH diagrams.

Texts/References

  • Anderson, G.M. Thermodynamics of Natural Systems, Cambridge University Press, 2005
  • Winter, J. D. Introduction to Igneous and Metamorphic Petrology. 2nd Ed. Prentice-Hall India, 2010
  • Drever, J.I. The Geochemistry of Natural Waters, 3rd Edn., Prentice Hall, 1997
  • Faure, G. Principles of Isotope Geology, 2nd Edn., John Wiley, 1986
  • Mason, B. and Moore, C. B. Principles of Geochemistry, 4th Edn., John Wiley, 1982
  • Wood, B.J. and Fraser, D.G. Elementary Thermodynamics for Geologists. Oxford, 1977